Dissolved organic matter in surface runoff in the Loess Plateau of China: The role of rainfall events and land-use     

Zhongwu Li  Hao Peng  Binggeng Xie  Chun Liu  Xiaodong Nie  Danyang Wang  Mei Huang  Haibing Xiao  Lin Shi  Xuqin Zhang  Jieyu Jiang 《水文研究》2020,34(6):1446-1459

Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes.  相似文献   

Response of soil aggregate disintegration to the different content of organic carbon and its fractions during splash erosion     

Hairu Li  Gang Liu  Ju Gu  Hong Chen  Hongqiang Shi  Mohamed A. M. Abd Elbasit  Feinan Hu 《水文研究》2021,35(2):e14060

Aggregate disintegration is a critical process in soil splash erosion. However, the effect of soil organic carbon (SOC) and its fractions on soil aggregates disintegration is still not clear. In this study, five soils with similar clay contents and different contents of SOC have been used. The effects of slaking and mechanical striking on splash erosion were distinguished by using deionized water and 95% ethanol as raindrops. The simulated rainfall experiments were carried out in four heights (0.5, 1.0, 1.5 and 2.0 m). The result indicated that the soil aggregate stability increased with the increases of SOC and light fraction organic carbon (LFOC). The relative slaking and the mechanical striking index increased with the decreases of SOC and LFOC. The reduction of macroaggregates in eroded soil gradually decreased with the increase of SOC and LFOC, especially in alcohol test. The amount of macroaggregates (>0.25 mm) in deionized water tests were significantly less than that in alcohol tests under the same rainfall heights. The contribution of slaking to splash erosion increased with the decrease of heavy fractions organic carbon. The contribution of mechanical striking was dominant when the rainfall kinetic energy increased to a range of threshold between 9 J m⁻² mm⁻¹ and 12 m⁻² mm⁻¹. This study could provide the scientific basis for deeply understanding the mechanism of soil aggregates disintegration and splash erosion.  相似文献   

Clinoforms and clinothems: Fundamental elements of basin infill     

Claudio Pellegrini  Stefano Patruno  William Helland-Hansen  Ronald J. Steel  Fabio Trincardi 《Basin Research》2020,32(2):187-205

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松辽盆地北部上二叠统林西组地球化学特征及地质意义     

张健  张海华  陈树旺  郑月娟  张德军  苏飞  黄欣 《吉林大学学报(地球科学版)》2020,50(2):518-530

为探讨松辽盆地北部林西组地球化学特征、沉积环境及构造背景，对该区黑富地1井所钻遇的上二叠统林西组暗色泥质板岩进行主量元素、微量元素和稀土元素测试分析，结果表明：样品主量元素平均质量分数SiO₂为65.05%、Al₂O₃为17.23%、CaO为2.58%、Na₂O为2.84%、K₂O为3.29%，K₂O/Na₂O值为0.20~3.48，A1₂O₃/（CaO+Na₂O）值为0.41~8.01；稀土元素w（∑REE）值介于80.68×10^-6~215.59×10^-6之间，平均值为173.41×10^-6，δEu值介于0.61~0.88之间，平均值为0.70，表现为Eu的负异常，δCe值介于0.91×10^-6~1.01×10^-6之间，为微弱的Ce负异常，LREE富集，HREE亏损；微量元素以亏损Nb、Ta、Sr，相对富集Rb、Ba、La、Ce、Pb、Nd、Sm为特征。样品元素分析和物源w（TiO₂）-w（Ni）、La/Th-w（Hf）等判别图解表明，林西组沉积物源具有多样性，主要来源于上地壳长英质物源，还有少量来自中、基性岩火成岩物源区。样品微量元素标准化蛛网图，稀土元素球粒陨石标准化配分模式图，K₂O/Na₂O-w（SiO₂）、Th-Co-Zr/10、F₂-F₁构造背景判别图及地球化学参数对比结果表明，松辽盆地北部林西组物源构造背景主要为活动大陆边缘和大陆岛弧，可能形成于靠近大陆岛弧的活动大陆边缘构造背景。林西组应形成于海陆过渡相到陆相环境，水体由半咸水逐渐转变为淡水。  相似文献   

浊积岩和砂质碎屑流岩关键识别标志及辽河盆地岩心实例^*          下载免费PDF全文

杨棵  朱筱敏  刘宇  刘兴周  郭峰 《古地理学报》2020,22(3):483-492

重力流是自然界中广泛存在的一种流体形式,不同学者基于不同切入点往往会提出多种重力流的划分方案。采用浊流和碎屑流的二分方案,对浊积岩和砂质碎屑流岩的沉积特征展开综述和探讨,旨在进一步概括这2类岩石的沉积特征,明确具有指示意义的最典型相标志。研究表明,在野外露头和钻井岩心中,可以通过以下典型特征鉴别浊积岩和砂质碎屑流岩: 砂岩内若发育以正粒序为特征的递变层理,则应该将其认定为浊积岩;若砂岩内发育泥岩撕裂屑、漂浮状泥砾或不含任何层理构造(块状砂岩),则应该将其认定为砂质碎屑流岩。这些特征是鉴别浊积岩和砂质碎屑流岩最可靠的标志。此外,变形层理、爬升波纹交错层理、波状层理、平行纹层、冲刷侵蚀界面、岩性突变界面和槽模等沉积构造也具有一定指示意义,出现这些特征时需要结合沉积背景、岩相的垂向组合关系和地球物理等资料进行综合判断。  相似文献   

鄂尔多斯盆地正宁地区三叠系延长组长9油层组成岩作用^*          下载免费PDF全文

沈默  朱筱敏  李程善  张文选  程逸凡  江梦雅 《古地理学报》2020,22(3):539-554

综合利用岩心、铸体薄片、扫描电镜等多种资料,对鄂尔多斯盆地正宁地区三叠系延长组长9油层组储集层的岩石类型、成岩作用类型、成岩相分布特征及主控因素进行了系统研究。延长组长9油层组储集层的岩石类型为细—中粒岩屑质长石砂岩和长石质岩屑砂岩,成岩作用类型主要为压实作用,同时还有绿泥石、方解石、铁方解石及硅质胶结作用,方解石交代作用和少量的溶蚀作用,储集层目前处于中成岩A期。根据层理频率和塑性颗粒含量将岩石划分为高频层理富片状塑性颗粒粉—细砂岩岩石相和低频层理富刚性矿物细—中砂岩岩石相,前者分布于水下分流河道边部,发育压实致密成岩相;后者形成于水下分流河道主河道和河口坝。根据砂体结构可划分为厚层单砂体和厚层多砂体。厚层单砂体为单期形成的河道或河口坝砂体,上部以方解石充填胶结成岩相为特征,下部以绿泥石衬边胶结成岩相为特征;厚层多砂体为多期砂体冲刷叠置形成,发育方解石绿泥石充填胶结成岩相。塑性颗粒含量对压实作用强度影响最大,叠加碳酸盐胶结致使储集层质量变差,而早期绿泥石环边胶结抑制压实作用,是有利储集层发育的重要条件。综合评价表明,延长组长9油层组有利储集层发育于绿泥石衬边胶结相,其次为绿泥石和方解石充填胶结相,最差储集层为方解石充填胶结相和压实致密相。  相似文献   

四川盆地广安地区中二叠统栖霞组岩石特征与沉积环境     

易海永  崔宝琛  王瑶琳  邱玉超  徐胜林  李乾 《吉林大学学报(地球科学版)》2020,50(2):454-464

四川盆地中二叠统栖霞组勘探发现系列油气，资源潜力巨大。但广安地区中二叠统栖霞组的岩石学特征及沉积环境研究薄弱。在野外地质调查的基础上，结合室内岩石学、岩相学等综合分析，对广安地区栖霞组碳酸盐岩岩石特征、沉积相类型及其古地理展布特征进行了系统研究。结果表明：广安地区栖霞组主要发育亮晶颗粒灰岩、亮晶生物碎屑灰岩、微晶生物碎屑灰岩、微晶颗粒灰岩、生物碎屑微晶灰岩、含生物碎屑微晶灰岩和泥晶灰岩7种岩石类型；碳酸盐岩颗粒主要以生物碎屑为主，部分层位发育球粒；古生物化石以三叶虫、腕足和有孔虫为主，同时可见棘皮类和藻类；栖霞组沉积期主要为碳酸盐岩台地沉积环境，其中栖霞组晚期（栖二段）台缘滩和台内滩较为发育，为该区油气成藏提供了有利条件。  相似文献   

Using Mesoproterozoic sedimentary geochemistry to reconstruct basin tectonic geography and link organic carbon productivity to nutrient flux from a Northern Australian large igneous Province     

Bo Yang  Alan S. Collins  Grant M. Cox  Amber J. M. Jarrett  Steven Denyszyn  Morgan L. Blades  Juraj Farkaš  Stijn Glorie 《Basin Research》2020,32(6):1734-1750

The Beetaloo Sub-basin, northern Australia, is considered the main depocentre of the 1,000-km scale Mesoproterozoic Wilton package of the greater McArthur Basin – the host to one of the oldest hydrocarbon global resources. The ca. 1.40–1.31 Ga upper Roper Group and the latest Mesoproterozoic to early Neoproterozoic unnamed group of the Beetaloo Sub-basin, together, record ca. 500 million years of depositional history within the North Australia Craton. Whole-rock shale Sm–Nd and Pb isotope data from these sediments reveal sedimentary provenance and their evolution from ca. 1.35 to 0.85 Ga. Furthermore, these data, together with shale major/trace elements data from this study and pyrolysis data from previous publications, are used to develop a dynamic tectonic geography model that links the organic carbon production and burial to an enhanced weathering of nutrients from a large igneous province. The ca. 1.35–1.31 Ga Kyalla Formation of the upper Roper Group is composed of isotopically evolved sedimentary detritus that passes up, into more isotopically juvenile Pb values towards the top of the formation. The increase in juvenile compositions coincides with elevated total organic carbon (TOC) contents of these sediments. The coherently enriched juvenile compositions and TOC the upper portions of the Kyalla Formation are interpreted to reflect an increase in nutrient supply associated with the weathering of basaltic sources (e.g. phosphorous). Possible, relatively juvenile, basaltic sources include the Wankanki Supersuite in the western Musgraves and the Derim Derim–Galiwinku large igneous province (LIP). The transition into juvenile, basaltic sources directly before a supersequence-bounding unconformity is here interpreted to reflect uplift and erosion of the Derim Derim–Galiwinku LIP, rather than an influx of southern Musgrave sources. A new baddeleyite crystallisation age of 1,312.9 ± 0.7 Ma provides both a tight constraint on the age of this LIP, along with its associated magmatic uplift, as well as providing a minimum age constraint for Roper Group deposition. The unconformably overlying lower and upper Jamison sandstones are at least 300 million years younger than the Kyalla Formation and were sourced from the Musgrave Province. An up-section increase in isotopically juvenile compositions seen in these rocks is interpreted to document the progressive exhumation of the western Musgrave Province. The overlying Hayfield mudstone received detritus from both the Musgrave and Arunta regions, and its isotopic geochemistry reveals affinities with other early Neoproterozoic basins (e.g. Amadeus, Victoria and Officer basins), indicating the potential for inter-basin correlations.  相似文献   

黔北正安地区五峰组—龙马溪组页岩气地质特征及有利区预测     

贺永忠  向坤鹏  安亚运  易成兴  杨忠琴  于宁 《中国地质调查》2020,7(3):21-29

为明确黔北正安地区上奥陶统五峰组至下志留统龙马溪组的页岩气地质特征,充分应用页岩气地质调查、重磁电、二维地震、地质调查井及测试分析等工作方法,开展黔北正安地区1:5万页岩气基础地质调查,对五峰组至龙马溪组富有机质页岩的分布、沉积环境、有机地球化学、岩石矿物、储集性能及含气性等特征进行分析研究,结果表明: 研究区五峰组—龙马溪组富有机质页岩为深水陆棚相沉积,主要分布有安场向斜、斑竹向斜和泥高向斜,厚度14.5~55 m,埋深0~3 200 m; 有机碳(TOC)含量1.0%~4.0%,有机质镜质体反射率(R_o)为1.82%~2.23%,有机质类型以Ⅰ型干酪根为主; 岩石主要由石英、长石和黏土矿物组成,脆性矿物含量高,一般大于50%; 孔隙度为2.03%~3.89%,渗透率为0.35×10^-5~1.86×10^-5μm²,表现为低孔、特低渗的特征; 最高含气量为2.88 m³/t,显示出较好的含气性特征。综合分析和评价圈出3个页岩气聚集有利区,分别为安场区块、斑竹区块和泥高区块,这为研究区页岩气进一步勘探开发指明了方向。  相似文献   

1980—2015年风蚀影响下中国北方土壤有机质与养分流失时空特征     

赵海鹏  宋宏权  刘鹏飞  李霄阳  王团徽 《地理研究》2019,38(11):2778-2789

中国北方干旱/半干旱区是全球主要的沙尘源区之一,风蚀造成的沙尘排放可导致大量的土壤有机质（SOM）与养分流失,并通过传输与沉降过程对其进行空间再分配,对空气质量、气候变化、植被生长及生物地球化学过程等具有重要影响。本文利用WRF/Chem（Weather Research Forecasting with Chemistry）v3.7.1大气化学传输模型,对1980—2015年间中国北方沙尘排放及其引起的SOM、全氮（TN）与全磷（TP）的时空变化过程进行了精细化模拟,探究了中国北方风蚀引起的SOM、TN与TP养分流失的时空变化特征。结果表明：① 1980—2015年来平均每年约有66.59 Tg的沙尘颗粒排放至大气;② 沙尘排放具有较大的时空差异,沙尘排放源区主要集中在新疆东部、内蒙古西部的巴丹吉林沙漠和腾格里沙漠等地区;③ 每年因沙尘排放引起的SOM、TN和TP流失量分别约为0.07 Tg、0.004 Tg和0.005 Tg;④ 1980—2015年间中国北方沙尘排放及其引起的SOM、TN与TP的流失量具有较强的年际波动,未呈现显著的趋势性变化特征。本研究对于认知风蚀在碳循环与养分循环过程中的作用,以及对深入了解中国北方的土地退化机理具有重要意义。  相似文献